
Hydraulic fracturing and the chemicals used
When the natural rate of gas production from a well is low, sometimes companies use a technique called hydraulic fracturing to improve gas flows.
Hydraulic fracturing has been used in the oil and gas industry for more than 50 years and in Australia for several decades.
when drilling wells, grout or cement is pumped between the well casing (a steel tube) and the hole back to the surface. This forms a barrier between the coal seams and any nearby aquifers.
Hydraulic fracturing involves mostly water and sand that is injected into wells at high pressure to crack the coal seams so gas can flow more freely. The sand holds open the cracks. The process is designed to only affect the target coal seam. Like farmers who use chemicals on crops, QGC uses chemicals with extreme care.
The small proportion of chemical additives in hydraulic fracturing fluid are needed to reduce friction, remove bacteria, dissolve some minerals and enhance the fluid’s ability to transport sand. They consist mainly of commonly used compounds like:
- Surfactants (in soap or toothpaste)
- Guar gum (in ice cream)
- Sodium hypochlorite (in swimming pools)
- Hydrochloric acid (also in swimming pools)
- Acetic acid (basis of vinegar)
All chemicals are handled according to strict procedures by trained personnel and are used in concentrations so low as to cause no adverse environmental impact. The chemical product safety data sheets (SDS) are supplied in Table 1 below. Table 2 provides stimulation chemical risk assessments, prepared by an independent and qualified consultancy, that:
- identify the hazards associated with proposed stimulation chemicals;
- consider potential exposure pathways and the risk of potential impacts; and,
- determine the required management measures.
Chemicals Used in Hydraulic Fracturing
| Service Company Name or Handling Name (links to SDS) | Main chemical components | Common uses | Main CAS# |
|---|---|---|---|
| Function: Biocide | - | - | - |
| BE-09 (PDF, 35 kB) | Tributyl tetradecyl phosphonium chloride | Biocide used industrial cleaning, oil field waters, papermaking | 81741-28-8 |
| BE-6 (PDF, 68 kB) | Bronopol | Eliminates bacteria in water | 52-51-7 |
| Magnacide 575, M298L (PDF, 136 kB) | Tetrakis (hydroxymethyl) phosphonium sulfate | Eliminates bacteria in water for farming uses | 55566-30-8 |
| M275, BPA68915 (PDF, 128 kB) | 3:1 CIT/MIT biocide, Magnesium Nitrate | Eliminates bacteria in water | 55965-84-9 |
| Sodium Hypochlorite, BE-7, M091 (PDF, 128 kB) | Sodium hypochlorite | Household bleach, disinfectants | 7681-52-9 |
| M300A (PDF, 48 kB) | Glutaraldehyde | Industrial water treatment, disinfectant | 111-30-8 |
| Clay control | - | - | - |
| KCL, M117 (PDF, 143 kB) | Potassium chloride | Fertilisers | 7447-40-7 |
| L071, ClayCare, ClayTreat-2C, Choline chloride (PDF, 85 kB) | Choline chloride | Agricultural feed additive | 67-48-1 |
| Corrosion inhibitor | - | - | - |
| B499, Gelatine (PDF, 210 kB) | Gelatine | Marshmallows, canned hams, desserts and dairy products, pharmaceuticals | 9000-70-8 |
| L058 (PDF, 102 kB) | Sodium erythorbate | Food additive used predominantly in meats, poultry, and soft drinks | 6381-77-7 |
| U042 (PDF, 119 kB) | Tetrasodium ethylenediaminetetraacetate | Food perservative, shampoo products, dentistry, cosmetics | 64-02-8, 1310-73-2, 5064-31-3 |
| Crosslinker | - | - | - |
| XLW-10A (PDF, 115 kB) | Borax, also known as sodium borate, sodium tetraborate, di-sodium tetraborate | Detergents, soaps | 1330-43-4, 107-21-1, 1310-73-2 |
| J480 (PDF, 105 kB) | Aliphatic acid salt | Fish bait additive, food preservatives | N/A . |
| J610 (PDF, 130 kB) | Potassium hydroxide | Manicure treatments, hair removal, soft soaps | 1310-58-3 |
| J604 (PDF, 107 kB) | Ethane-1,2-diol, Sodium tetraborate | Corrosion protection, antifreeze | 107-21-1, 1330-43-4 |
| Gel | |||
| J580 (PDF, 111 kB) | - | Food thickening agent | N/A |
| J594 (PDF, 110 kB) | Carbohydrate polymer derivative | None. Considered non hazardous. | - |
| J596 (PDF, 136 kB) | 2,2',2"-nitrilotriethanol | Laundry detergents, dishwashing liquids, general cleaners, shaving cream. | 102-71-6, 1330-43-4, 7699-43-6 |
| J450 (PDF, 111 kB) | 2,2',2"-nitrilotriethanol | Laundry detergents, dishwashing liquids, general cleaners, shaving cream. | 102-71-6, 1330-43-4, 7699-43-6 |
| Service Company Name or Handling Name (links to SDS) | Main chemical components | Common uses | Main CAS# |
| Function: Gel breaker | - | - | - |
| GBW-30 (PDF, 74 kB) | Carbohydrates, hemicellulase enzyme | Food additives, coffee processing | 9012-54-8 |
| J218, J479, GBW-5 (PDF, 111 kB) | Diammonium peroxidisulphate | Hair bleach, household cleaners, etching copper, printed circuit boards | 7727-54-0 |
| J134 (PDF, 107 kB) | Hemicellulase enzyme | Food additives, coffee processing | 9012-54-8 |
| J318 (PDF, 130 kB) | 2,2`,2"-nitrilotriethanol | liquid laundry detergents, dishwashing liquids, general cleaners, hand cleaners, polishes, metalworking fluids, paints, shaving cream and printing inks | 102-71-6 |
| J481 (PDF, 109 kB) | Sodium bromate | Hair pigments, clothes dyeing | 7789-38-0 |
| J490 (PDF, 142 kB) | Sodium bromate | Hair pigments, clothes dyeing | 7789-38-0 |
| Gel stabiliser | - | - | - |
| J589 (PDF, 147 kB) | Propan-2-ol | Keyboard, LCD screen, whiteboard and eyeglasses cleaner | 67-63-0 |
| J511 (PDF, 97 kB) | Aliphatic polyol | N/A. | N/A. |
| Friction Reducer | - | - | - |
| FRW-16 (PDF, 81 kB) | 1-Propanesulfonic acid, 2-methyl-2-[(1-oxo-2-propen-1-yl)amino], sodium salt (1:1) homopolymer | Water treatment, Thickener, Personal care products | 35641-59-9 |
| J353L (PDF, 105 kB) | Sodium thiosulphate | Preservative, stain remover, bleach and chlorine remover | 7772-98-7 |
| J568 (PDF, 119 kB) | Butyl Diglycol | Printing ink, surface cleaners, foam fire extinguishers | 112-34-5 |
| J599 (PDF, 106 kB) | Tetraethylenepentamine | Adhesives, agriculture, veterinary and detergents | 112-57-2, 4067-16-7, 112-24-3 |
| Other | - | - | - |
| Nitrogen (PDF, 132 kB) | Nitrogen | Refrigeration, supercooling, inert gas | 7727-37-9 |
| Carbon Dioxide (PDF, 114 kB) | Carbon Dioxide | Dry ice | 124-38-9 |
| Sodium Chloride, Rock Salt, D044 (PDF, 130 kB) | Sodium chloride | Table salt | 7647-14-5 |
| Fluorobenzoic acids (ZIP) | Fluorobenzoic acids | Groundwater tracers | 385-00-2, 445-29-4, 1583-58-0 |
| Oxygen Scavenger | - | - | - |
| Oxygon (PDF, 78 kB) | Organic acid salt | Removal of dissolved oxygen in fluids, meat processing | 6381-77-7 |
| J528 (PDF, 85 kB) | Organic polymer | Biodegradable plastics (eg. Biodegradeable plastic bags, sheets, cups) | 9051-89-2 |
| J554 (PDF, 49 kB) | Aliphatic synthetic polymer | Carpenters glue | N/A |
| pH buffer | - | - | - |
| M003, Soda Ash (PDF, 119 kB) | Sodium Carbonate | Neutralise acids, water softening | 497-19-8 |
| Sodium Hydroxide, U028 (PDF, 127 kB) | Sodium Hydroxide | Manufacturing of paper, textiles, drinking water, soaps, detergents, drain cleaner | 1310-73-2 |
| BF-3 (PDF, 79 kB) | Sodium Bicarbonate | Baking soda | 144-55-8 |
| BF-7L (PDF, 80 kB) | Potassium carbonate | Additive in soaps, wines, dyes, glass | 584-08-7 |
| Acetic Acid, BF10L, L401 (PDF, 60 kB) | Acetic acid | Vinegar | 64-19-7 |
| HCL (PDF, 94 kB) | Hydrochloric Acid | Swimming pool pH control | 7647-01-0 |
| FE-300 (PDF, 88 kB) | Citric Acid | Naturally occurring in citrus fruits, flavouring, cosmetics | 77-92-9 |
| Scale inhibitor | - | - | - |
| L065 (PDF, 90 kB) | Calcium Chloride, 1,2-Ethanediol | Brine, desiccant | 10043-52-4, 107-21-1 |
| Surfactant | - | - | - |
| F112 (PDF, 135 kB) | Polyethylene glycol monohexyl ether | Cleaning fluids, paints, coatings, silk screening inks | 31726-34-8 |
| Foam Stabiliser | - | - | - |
| B271 (PDF, 126 kB) | beta-Alanine, N-coco alkyl derivs., sodium salts | Carwash foams | 68608-68-4, 111-76-2, 67-63-0 |
| Proppant | - | - | - |
| Sand (PDF, 368 kB) | quartz | Construction | 14808-60-7 |
| Carboprop (PDF, 109 kB) | Corundum, Mullite | Construction | 1302-93-8 |
| NRTCarboprop (PDF, 110 kB) | - | - | - |
Stimulation Risk Assessment Reports
Note: The above tables are periodically updated with new chemical products and also to remove some that are obsolete. Chemical products are retained on the QGC website for at least a year following their use in hydraulic fracturing. For information about historical chemicals used in hydraulic fracturing please contact us.